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Coating could mean the end of foggy glasses

(Credit: Getty Images)

A new coating prevents fogging on transparent surfaces, researchers report.

Going into a warm humid environment from the cold can cause eyeglasses or camera lenses to fog up, but the new coating uses sunlight to clear things up.

Since the only energy source required is the sun, the coating works especially well for wearable items such as glasses and goggles. Researchers made the transparent durable coating, which is just a few nanometers thick, of gold nanoparticles embedded in non-conductive titanium oxide.

anti-fog light
Shining a light through the center of a transparent pane researchers coated with nanoparticles prevented the lit area from fogging. (Credit: Christopher Walker/ETH Zurich)

“Our coating absorbs the infrared component of sunlight along with a small part of the visible sunlight and converts the light into heat,” says lead author Christopher Walker, a doctoral student working with Dimos Poulikakos, a professor at ETH Zurich. The process heats the surface up about 3 to 4 degrees Celsius—the difference in temperature that prevents fogging.

Heat also solves the problem of fogging on car windows. Warm air from the in-vehicle heating system heats the front windshield, while the rear window uses a grid of electrical heating elements. Unlike these methods, the researchers’ new coating works passively.

“Normally, it’s dark surfaces that absorb light and convert it into heat,” says Efstratios Mitridis, another doctoral student in Poulikakos’s group. “But we’ve created a transparent surface that has the same effect.”

Condensation occurs on a surface whenever there is a sudden drop in temperature or increase in humidity, forming tiny droplets of water that disperse incident light in different directions in much the same way as atmospheric fog.

As an alternative to using heat to prevent fogging, hydrophilic agents can coat susceptible surfaces. Because they attract water, these agents ensure that the condensation forms an even thin film of liquid over the surface rather than separate droplets. Anti-fog sprays for glasses usually work on this principle.

Now, tests have shown that when exposed to sunlight, fogged surfaces coated with gold nanoparticles and titanium oxide clear four times faster than surfaces treated with a normal anti-fog agent.

“Spray treatments often lose their effect after a while because the anti-fog film dries up or becomes unevenly distributed,” Walker says. “A durable coating like ours lasts much longer than a spray treatment, which you have to apply virtually on a daily basis.”

The scientists say they plan to bring the new method to market, in collaboration with an industry partner.

“We’re looking to refine our already robust coating to ensure it lasts for years, and we want to take the technology from lab scale to industry scale,” Walker says.

Source: ETH Zurich

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To generate more solar power, put this material on glass

(Credit: Richard Lunt/Michigan State)

Transparent solar materials on windows could gather as much energy as bulkier rooftop solar units, say researchers.

“Highly transparent solar cells represent the wave of the future for new solar applications…”

The authors of a new paper argue that widespread use of such highly transparent solar applications, together with the rooftop units, could nearly meet US electricity demand and drastically reduce the use of fossil fuels.

“Highly transparent solar cells represent the wave of the future for new solar applications,” says Richard Lunt, an associate professor of chemical engineering and materials science at Michigan State University. “We analyzed their potential and show that by harvesting only invisible light, these devices can provide a similar electricity-generation potential as rooftop solar while providing additional functionality to enhance the efficiency of buildings, automobiles, and mobile electronics.”

Lunt and colleagues pioneered the development of a transparent luminescent solar concentrator that, when placed on a window, creates solar energy without disrupting the view. The thin, plastic-like material can be used on buildings, car windows, cell phones, or other devices with a clear surface.

The solar-harvesting system uses organic molecules developed by Lunt and his team to absorb invisible wavelengths of sunlight. The researchers can “tune” these materials to pick up just the ultraviolet and the near-infrared wavelengths that then convert this energy into electricity.

Moving global energy consumption away from fossil fuels will require such innovative and cost-effective renewable energy technologies. Only about 1.5 percent of electricity demand in the United States and globally is produced by solar power.

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In terms of overall electricity potential, however, the authors note that there is an estimated 5 billion to 7 billion square meters of glass surface in the United States. With that much glass to cover, transparent solar technologies have the potential of supplying some 40 percent of energy demand in the US—about the same potential as rooftop solar units.

“The complimentary deployment of both technologies,” Lunt says, “could get us close to 100 percent of our demand if we also improve energy storage.”

Lunt says highly transparent solar applications are recording efficiencies above 5 percent, while traditional solar panels typically are about 15 percent to 18 percent efficient. Although transparent solar technologies will never be more efficient at converting solar energy to electricity than their opaque counterparts, they can get close and offer the potential to cover a lot more additional surface area, he says.

Right now, transparent solar technologies are only at about a third of their realistic overall potential, Lunt adds.

“That is what we are working towards,” he says. “Traditional solar applications have been actively researched for over five decades, yet we have only been working on these highly transparent solar cells for about five years. Ultimately, this technology offers a promising route to inexpensive, widespread solar adoption on small and large surfaces that were previously inaccessible.”

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The researchers published their work in the journal Nature Energy.

The National Science Foundation and the US Department of Education funded the study.

Lunt’s coauthors are from Michigan State and Ubiquitous Energy Inc., a company Lunt cofounded with Barr to commercialize transparent solar technologies.

Source: Michigan State University