Scientists have developed a simple way to produce conductive, three-dimensional objects from graphene foam.
The squishy solids look and feel something like a child’s toy but offer new possibilities for energy storage and flexible electronic sensor applications, according to James Tour, a chemist at Rice University, whose lab developed the method.
The technique, detailed in Advanced Materials, is an extension of Tour lab work that produced the first laser-induced graphene (LIG) in 2014 by heating inexpensive polyimide plastic sheets with a laser.
The laser burns halfway through the plastic and turns the top into interconnected flakes of 2D carbon that remain attached to the bottom half. LIG can be made in macroscale patterns at room temperature.
“Now we have built a prototype machine that lets us make graphene foam into 3D objects through automated successive layering and laser exposure,” Tour says. “This truly brings graphene into the third dimension without furnaces or the need for metal catalysts, and our process is easily scaled.”
The new method is based on laminated object manufacturing, in which layers of a material are assembled and then cut to shape. In this case, the bottom LIG layer remains attached to its polyimide base. A second layer is coated with ethylene glycol and placed face down on the first, like a jelly sandwich. Its polyimide top is then burned into graphene; the process is repeated until the block is complete.
The ethylene glycol binder is evaporated away on a hot plate, and any remaining polyimide can be removed in a furnace. That leaves a pristine, spongy carbon block, says Duy Xuan Luong, a graduate student at Rice and co-lead author of the paper. The researchers stacked up to five layers of foam and then used a custom-built fiber lasing system on a modified 3D printer to mill the block into complex shapes.
The lab assembled proof-of-concept lithium-ion capacitors that used 3D LIG as both anodes and cathodes. The anode’s gravimetric capacity of 354 milliamp hours per gram neared the theoretical limit of graphite, while the cathode’s capacity exceeded the average capacity of other carbon materials. Full test cells retained about 70 percent of their capacity after 970 charge-discharge cycles.
“This is excellent performance in these new-generation lithium-ion capacitors, which capture the best properties of lithium-ion batteries and capacitor hybrids,” Tour says.
The researchers then infused a block of 3D LIG with liquid polydimethylsiloxane through its 20- to 30-nanometer pores. This created a stronger, still-flexible, conductive material without changing the original foam’s shape. From this material, they made a flexible sensor that accurately recorded the pulse from the wrist of a volunteer and says further calibration of the device would let them extract blood pressure from the pulse waveform.
Additional coauthors are from Rice and the Korea Basic Science Institute. The Air Force Office of Scientific Research and the Vietnam Education Foundation supported the research.
Source: Rice University