Scientists have modeled a nanoscale “sandwich” with two slices of atom-thick graphene around nanoclusters of magnesium oxide. This arrangement gives the super-strong, conductive material expanded optoelectronic properties.
Rice materials scientist Rouzbeh Shahsavari and his colleagues built computer simulations of the compound and found it would offer features suitable for sensitive molecular sensing, catalysis, and bio-imaging. Their work could help researchers design a range of customizable hybrids of two- and three-dimensional structures with encapsulated molecules, Shahsavari says.
The scientists were inspired by experiments elsewhere in which various molecules were encapsulated using van der Waals forces to draw components together. The new study was the first to take a theoretical approach to defining the electronic and optical properties of one of those “made” samples, two-dimensional magnesium oxide in bilayer graphene, Shahsavari says.
“We knew if there was an experiment already performed, we would have a great reference point that would make it easier to verify our computations, thus allowing more reliable expansion of our computational results to identify performance trends beyond the reach of experiments,” Shahsavari says.
“There is no single material that can solve all the technical problems of the world.”
Graphene on its own has no band gap—the characteristic that makes a material a semiconductor. But the hybrid does, and this band gap could be tunable, depending on the components, Shahsavari says. The enhanced optical properties are also tunable and useful, he says.
“We saw that while this single flake of magnesium oxide absorbed one kind of light emission, when it was trapped between two layers of graphene, it absorbed a wide spectrum. That could be an important mechanism for sensors,” he says.
Shahsavari says his group’s theory should be applicable to other two-dimensional materials, like hexagonal boron-nitride, and molecular fillings. “There is no single material that can solve all the technical problems of the world,” he says. “It always comes down to making hybrid materials to synergize the best features of multiple components to do a specific job. My group is working on these hybrid materials by tweaking their components and structures to meet new challenges.”
The research appears in the journal Nanoscale.
Farzaneh Shayeganfar, a visiting research scientist at Rice and researcher at Shahid Rajaee Teacher Training University in Tehran, Iran, is lead author of the paper. Additional coauthors are from the University of Antwerp in Belgium.
Rice University and the Iran Science Elites Federation supported the research. Computing resources came from Rice’s National Science Foundation-supported DAVinCI supercomputer administered by Rice’s Center for Research Computing and were procured in partnership with Rice’s Ken Kennedy Institute for Information Technology.
Source: Rice University