chemistry

Super-heavy element 117 joins periodic table

element117_blue_big_1

An international team of scientists has identified element 117 (illustrated above and below), a super-heavy element that strengthens the likelihood that still more massive elements may form an “island of stability” of novel materials with exotic and as yet unknown applications. “These studies will test theoretical predictions that elements beyond 112 could have unexpected positions in the periodical table of elements,” says Joe Hamilton of Vanderbilt University. (Courtesy: Lawrence Livermore National Laboratory)

VANDERBILT (US)—Discovery of the super-heavy element 117 provides new information about the basic organization of matter and strengthens the likelihood that still more massive elements may form an “island of stability”: a cluster of stable, super-heavy elements that could form novel materials with exotic and as yet unimagined scientific and practical applications.

The report of the discovery made by an international team of scientists is published in the journal Physical Review Letters.

element117_yellow_big_2

Atomic nuclei consist of protons and neutrons. Elements are determined by the number of positively charged protons in their nuclei. Atoms with the same number of protons but different numbers of neutrons have the same chemical properties but weigh slightly differently and are called isotopes.

The lightest natural element is hydrogen with one proton. The heaviest natural element is uranium with 92 protons.

In recent years, physicists at the Joint Institute for Nuclear Research in Dubna, Russia, led by Yuri Oganessian have developed a method of making super-heavy elements by smashing calcium ions, with 20 protons, into various targets.

In this way they had discovered elements 114, 115, 116, and 118. They were unable to create element 117, however, because the target required was itself a very exotic and expensive element, berkelium, with 97 protons.

“When I talked to the people at Oak Ridge National Laboratory who have the ability to create berkelium, I was told it would cost $3.5 million,” says Joe Hamilton, the Landon C. Garland Distinguished Professor of Physics at Vanderbilt University. “That was too much, so I kept looking.”

After several years of checking regularly with his Oak Ridge contacts, Hamilton finally saw the opportunity he was looking for when he heard that colleagues at Oak Ridge had agreed to make the element californium for a commercial project.

He realized that berkelium could be extracted at the same time so he worked out a deal that would produce the target material.

The two-year experimental campaign began at the High Flux Isotope Reactor in Oak Ridge with a 250-day irradiation in the world’s most intense neutron flux that produced 22 milligrams of berkelium, followed by 90 days of processing at Oak Ridge to separate and purify the berkelium.

The material was sent to the Research Institute for Advanced Reactors in Dimitorovgrad, Russia, for target preparation and then transferred to Dubna, where it was placed in one of he world’s most powerful heavy ion accelerators.

Six atoms of element 117 were produced after 150 days of bombardment. The data from these six events were analyzed at Dubna and Livermore, and the results were double-checked by the entire team.

Element 117 is the 26th new element that has been added to the periodic table since 1940. As scientists created heavier and heavier artificial elements, they became increasingly unstable until reaching a limit at element 113.

“These new elements provide important tests of nuclear theories,” says Hamilton. “The longer lifetimes of the new isotopes observed in our discovery of element 117 makes it possible to study the chemistry of these super-heavy elements.

“These studies will test theoretical predictions that elements beyond 112 could have unexpected positions in the periodical table of elements.”

Vanderbilt University news: www.vanderbilt.edu/News

Related Articles