Plant extract works as cathode for batteries

RICE (US) — Researchers say a plant extract can be turned into a highly effective, natural cathode for lithium-ion batteries.

The madder plant, Rubia tinctorum, is a good source of purpurin, an organic dye that has been used on fabrics since ancient times.

Arava Leela Mohana Reddy, a research scientist at Rice University, and colleagues came across purpurin while testing a number of organic molecules for their ability to electrochemically interact with lithium and found purpurin most amenable to binding lithium ions.

Madder, a climbing plant, has been used since ancient times to create dye for fabrics. (Credit: chemazgz/Flickr)

Purpurin, left, extracted from madder root, center, is chemically lithiated, right, for use as an organic cathode in batteries. The material was developed as a less expensive, easier-to-recycle alternative to cobalt oxide cathodes now used in lithium-ion batteries. (Credit: Ajayan Group/Rice University)


With the addition of 20 percent carbon to add conductivity, the team built a half-battery cell with a capacity of 90 milliamp hours per gram after 50 charge/discharge cycles. The cathodes can be made at room temperature, Reddy says.

The discovery is the subject of a paper in Nature’s open-access journal Scientific Reports.

The goal, according to Reddy, lead author of the paper, is to create environmentally friendly batteries that solve many of the problems with lithium-ion batteries in use today.

“Green batteries are the need of the hour, yet this topic hasn’t really been addressed properly,” Reddy says. “This is an area that needs immediate attention and sustained thrust, but you cannot discover sustainable technology overnight.

“The current focus of the research community is still on conventional batteries, meeting challenges like improving capacity. While those issues are important, so are issues like sustainability and recyclability.”

While lithium-ion batteries have become standard in conventional electronics since their commercial introduction in 1991, the rechargeable units remain costly to manufacture, Reddy notes.

“They’re not environmentally friendly. They use cathodes of lithium cobalt oxide, which are very expensive. You have to mine the cobalt metal and manufacture the cathodes in a high-temperature environment. There are a lot of costs.

“And then, recycling is a big issue,” he adds. “In 2010, almost 10 billion lithium-ion batteries had to be recycled, which uses a lot of energy. Extracting cobalt from the batteries is an expensive process.”

Green batteries

Reddy says the chemistry involved in using purpurin to create a cathode “is really simple.”

He suggests agricultural waste may be a source of purpurin, as may other suitable molecules, which makes the process even more economical.

Innovation in the battery space is needed to satisfy future demands and counter environmental issues like waste management, “and hence we are quite fascinated by the ability to develop alternative electrode technologies to replace conventional inorganic materials in lithium-ion batteries,” says Pulickel Ajayan, a professor of mechanical engineering, materials science, and chemistry.

“We’re interested in developing value-added chemicals, products and materials from renewable feedstocks as a sustainable technology platform,” says co-lead author George John, a professor of chemistry at the City College of New York-CUNY and an expert on bio-based materials and green chemistry. “The point has been to understand the chemistry between lithium ions and the organic molecules. Now that we have that proper understanding, we can tap other molecules and improve capacity.”

Recent work by the Ajayan Group combines silicon and a porous nickel current collector in a way that has proven effective as a high-capacity anode, the other electrode in a lithium-ion battery. That research was reported recently in the American Chemical Society journal Nano Letters.

But Reddy hopes to formulate completely green batteries. The team is looking for organic molecules suitable for anodes and for an electrolyte that doesn’t break the molecules down. He fully expects to have a working prototype of a complete organic battery within a few years.

“What we’ve come up with should lead to much more discussion in the scientific community about green batteries,” he says.

The Army Research Office funded the work.

Source: Rice University