U. TORONTO (CAN) — A new way to tightly pack quantum dots together has yielded the most efficient solar cell of its kind.
Quantum dots are nanoscale semiconductors that capture light and convert it into electrical energy. Because of their small scale, the dots can be sprayed onto flexible surfaces, including plastics.
This enables the production of solar cells that are less expensive than the existing silicon-based version.
Transmission electron microscope image showing a number of quantum dots spaced apart from one another due to the bulk of organic ligands—the halos around the bright solid circles. (Credit: University of Toronto)
“We figured out how to shrink the wrappers that encapsulate quantum dots down to the smallest imaginable size—a mere layer of atoms,” says Ted Sargent, corresponding author on the work and professor of nanotechnology at the University of Toronto.
The discovery is reported in the latest issue of Nature Materials.
A crucial challenge for the field has been striking a balance between convenience and performance. The ideal design is one that tightly packs the quantum dots together. The greater the distance between quantum dots, the lower the efficiency.
Until now, quantum dots have been capped with organic molecules that separate the nanoparticles by a nanometer. On the nanoscale, that is a long distance for electrons to travel.
To solve this problem, researchers from Toronto, King Abdullah University of Science and Technology (KAUST), and Penn State utilized inorganic ligands. These sub-nanometer-sized atoms bind to the surfaces of the quantum dots and take up less space.
The combination of close packing and charge trap elimination enabled electrons to move rapidly and smoothly through the solar cells, thus providing record efficiency.
“We wrapped a single layer of atoms around each particle. This allowed us to pack well-passivated quantum dots into a dense solid,” says Jiang Tang, the first author of the paper who conducted the research while a post-doctoral fellow at Toronto.
“Our team at Penn State proved that we could remove charge traps – locations where electrons get stuck—while still packing the quantum dots closely together,” says Professor John Asbury of Penn State, a co-author of the work.
“[W]e used visualization methods with sub-nanometer resolution and accuracy to investigate the structure and composition of the passivated quantum dots,” says co-author Aram Amassian of KAUST in Saudi Arabia.
“We proved that the inorganic passivants were tightly correlated with the location of the quantum dots and that it was the chemical passivation, rather than nanocrystal ordering, that led to the remarkable colloidal quantum dot solar cell performance,” he adds.
“It is very impressive that the team was able to make solar cells with power conversion efficiency up to 6 percent from quantum dots,” states Michael McGehee, a professor at Stanford University, a world-renowned expert in solution-processed organic solar cells.
“There is a lot of surface area in these films that could have dangling bonds which would hinder the performance of solar cells by creating traps states.
The team’s quantum dots had the highest electrical currents and the highest overall power conversion efficiency ever seen in colloidal quantum dot (CQD) solar cells. The performance results were certified by an external laboratory, Newport, which is accredited by the US National Renewable Energy Laboratory.
“This work proves the power of inorganic ligands in building practical devices,” says Dmitri Talapin, a professor at the University of Chicago, a pioneer in inorganic ligands and materials chemistry. “This new surface chemistry provides the path toward both efficient and stable quantum dot solar cells. It should also impact other electronic and optoelectronic devices that utilize colloidal nanocrystals. Advantages of the all-inorganic approach include vastly improved electronic transport and a path to long-term stability.”
As a result of the potential of this research discovery, a technology licensing agreement has been signed by Toronto and KAUST, brokered by MaRS Innovations (MI), which will enable the global commercialization of this new technology.
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