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Electrons with opposite momenta and spins pair up via lattice vibrations at low temperatures in two-dimensional boron and give it superconducting properties. (Credit: Evgeni Penev/Rice University)

materials science

Flat boron may be the world’s only 2D superconductor

Scientists have determined that two-dimensional boron is a natural low-temperature superconductor. In fact, it may be the only 2D material with such potential.

Theoretical physicist Boris Yakobson and colleagues at Rice University published their calculations that show atomically flat boron is metallic and will transmit electrons with no resistance. The work appears in journal Nano Letters.

The hitch, as with most superconducting materials, is that it loses its resistivity only when very cold, in this case between 10 and 20 kelvins (roughly, minus-430 degrees Fahrenheit). But for making very small superconducting circuits, it might be the only game in town.

The basic phenomenon of superconductivity has been known for more than 100 years, said Evgeni Penev, a research scientist in the Yakobson group, but had not been tested for its presence in atomically flat boron.

“It’s well-known that the material is pretty light because the atomic mass is small,” Penev says. “If it’s metallic too, these are two major prerequisites for superconductivity. That means at low temperatures, electrons can pair up in a kind of dance in the crystal.”

[It took 2 decades to make this gyroidal superconductor]

“Lower dimensionality is also helpful,” Yakobson says. “It may be the only, or one of very few, two-dimensional metals. So there are three factors that gave the initial motivation for us to pursue the research. Then we just got more and more excited as we got into it.”

Electrons with opposite momenta and spins effectively become Cooper pairs; they attract each other at low temperatures with the help of lattice vibrations, the so-called “phonons,” and give the material its superconducting properties, Penev explains.

“Superconductivity becomes a manifestation of the macroscopic wave function that describes the whole sample. It’s an amazing phenomenon,” he says.

The first samples of boron

It wasn’t entirely by chance that the first theoretical paper establishing conductivity in a 2D material appeared at roughly the same time the first samples of the material were made by laboratories in the United States and China. In fact, an earlier paper by the Yakobson group had offered a road map for doing so.

That 2D boron has now been produced is a good thing, according to Yakobson and lead authors Penev and Alex Kutana, a postdoctoral researcher at Rice.

“We’ve been working to characterize boron for years, from cage clusters to nanotubes to planer sheets, but the fact that these papers appeared so close together means these labs can now test our theories,” Yakobson says.

“In principle, this work could have been done three years ago as well,” he adds. “So why didn’t we? Because the material remained hypothetical; okay, theoretically possible, but we didn’t have a good reason to carry it too far.

[Crinkles give 2D boron some cool powers]

“But then last fall it became clear from professional meetings and interactions that it can be made. Now those papers are published. When you think it’s coming for real, the next level of exploration becomes more justifiable,” Yakobson says.

Boron atoms can make more than one pattern when coming together as a 2D material, another characteristic predicted by Yakobson and his team that has now come to fruition. These patterns, known as polymorphs, may allow researchers to tune the material’s conductivity “just by picking a selective arrangement of the hexagonal holes,” Penev says.

He also notes boron’s qualities were hinted at when researchers discovered more than a decade ago that magnesium diborite is a high-temperature electron-phonon superconductor.

“People realized a long time ago the superconductivity is due to the boron layer,” Penev says. “The magnesium acts to dope the material by spilling some electrons into the boron layer. In this case, we don’t need them because the 2D boron is already metallic.”

Penev suggests that isolating 2D boron between layers of inert hexagonal boron nitride (aka “white graphene”) might help stabilize its superconducting nature.

The Office of Naval Research and the Department of Energy Office of Basic Energy Sciences supported the research.

Source: Rice University


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