RICE (US) — Hybrid ribbons thousands of times thinner than a sheet of paper could speed the development of powerful lithium-ion batteries, researchers report.
The material, made of vanadium oxide (VO2) and graphene, is a superior cathode for batteries that could supply both high energy density and significant power density. The ribbons have potential that far outweighs current materials for their ability to charge and discharge very quickly.
Cathodes built into half-cells for testing fully charged and discharged in 20 seconds and retained more than 90 percent of their initial capacity after more than 1,000 cycles.
“This is the direction battery research is going, not only for something with high energy density but also high power density,” says Pulickel Ajayan, materials scientist at Rice University. “It’s somewhere between a battery and a supercapacitor.”
The ribbons also have the advantage of using relatively abundant and cheap materials, he says. “This is done through a very simple hydrothermal process, and I think it would be easily scalable to large quantities.”
As reported in the journal Nano Letters, vanadium oxide has long been considered a material with great potential, and in fact vanadium pentoxide has been used in lithium-ion batteries for its special structure and high capacity. But oxides are slow to charge and discharge, due to their low electrical conductivity. The high-conductivity graphene lattice that is literally baked in solves that problem nicely by serving as a speedy conduit for electrons and channels for ions.
The atom-thin graphene sheets bound to the crystals take up very little bulk. In the best samples, fully 84 percent of the cathode’s weight was the lithium-slurping VO2, which held 204 milliamp hours of energy per gram. The researchers, led by Rice graduate student Yongji Gong and lead author Shubin Yang, believe that to be among the best overall performance ever seen for lithium-ion battery electrodes.
“One challenge to production was controlling the conditions for the co-synthesis of VO2 ribbons with graphene,” Yang says. The process involved suspending graphene oxide nanosheets with powdered vanadium pentoxide (layered vanadium oxide, with two atoms of vanadium and five of oxygen) in water and heating it in an autoclave for hours.
The vanadium pentoxide was completely reduced to VO2, which crystallized into ribbons, while the graphene oxide was reduced to graphene, Yang says. The ribbons, with a web-like coating of graphene, were only about 10 nanometers thick, up to 600 nanometers wide and tens of micrometers in length.
“These ribbons were the building blocks of the three-dimensional architecture,” Yang says. “This unique structure was favorable for the ultrafast diffusion of both lithium ions and electrons during charge and discharge processes. It was the key to the achievement of excellent electrochemical performance.”
In testing the new material, Yang and Gong found its capacity for lithium storage remained stable after 200 cycles even at high temperatures (167 degrees Fahrenheit) at which other cathodes commonly decay, even at low charge-discharge rates.
“We think this is real progress in the development of cathode materials for high-power lithium-ion batteries,” Ajayan says, suggesting the ribbons’ ability to be dispersed in a solvent might make them suitable as a component in the paintable batteries developed in his lab.
The US Army Research Office, the Office of Naval Research, and the National Science Foundation funded the work.
Source: Rice University