"While water contamination can be mitigated by treatment to a certain degree, our findings indicate that disposal of wastewater from both conventional and unconventional oil and gas operations has degraded the surface water and sediments," says Nathaniel R. Warner. "This could be a long-term legacy of radioactivity." (Credit: Kordite/Flickr)

Fracking linked to radioactive river water in Pennsylvania

Tests show high levels of radioactivity in river water and sediments at a site where treated water from oil and gas operations is discharged into a western Pennsylvania creek.

“Radium levels were about 200 times greater in sediment samples collected where the Josephine Brine Treatment Facility discharges its treated wastewater into Blacklick Creek than in sediment samples collected just upstream of the plant,” says Avner Vengosh, professor of geochemistry and water quality at Duke University’s Nicholas School of the Environment.

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This map (view larger) shows the locations of 74 facilities permitted in 2010 to accept and treat Marcellus Shale produced and flowback waters (red squares), the majority of which are located in the Ohio River Basin (light blue shading). The current study focused on Josephine Brine Treatment Facility (black square), a centralized waste treatment facility in western Pennsylvania where treated wastewater is discharged into Blacklick Creek (see Figure S1 for details). Background measurements (yellow circles) were collected in 2011 at locations upstream or more than 1 kilometer downstream of any permitted facilities. (Credit: Avner Vengosh/Duke University)

Researchers examined the quality of shale gas wastewater from hydraulic fracturing and the stream water above and below the disposal site. Their study found that some of the discharged effluent is derived from the Marcellus shale gas flowback water, which is naturally high in salinity and radioactivity.

High concentrations of some salts and metals were also observed in the stream water.

“The treatment removes a substantial portion of the radioactivity, but it does not remove many of the other salts, including bromide,” Vengosh says. “When the high-bromide effluents are discharged to the stream, it increases the concentrations of bromide above the original background levels.

“This is significant because bromide increases the risks for formation of highly toxic disinfection byproducts in drinking water treatment facilities that are located downstream.”

“The radioactivity levels we found in sediments near the outflow are above management regulations in the US and would only be accepted at a licensed radioactive disposal facility,” says Robert B. Jackson, professor of environmental science at Duke. “The facility is quite effective in removing metals such as barium from the water but concentrates sulfates, chlorides, and bromides. In fact this single facility contributes four-fifths of the total downstream chloride flow at this point.”

Stop releasing wastewater?

The team also analyzed stream-bottom sediments for radium isotopes that are typically found in Marcellus wastewater. Their findings are reported in the journal Environmental Science and Technology.

“Although the facility’s treatment process significantly reduced radium and barium levels in the wastewater, the amount of radioactivity that has accumulated in the river sediments still exceeds thresholds for safe disposal of radioactive materials,” Vengosh says.

“Years of disposal of oil and gas wastewater with high radioactivity has created potential environmental risks for thousands of years to come.”

“While water contamination can be mitigated by treatment to a certain degree, our findings indicate that disposal of wastewater from both conventional and unconventional oil and gas operations has degraded the surface water and sediments,” says Nathaniel R. Warner, a recent PhD graduate of Duke who is now a postdoctoral researcher at Dartmouth College. “This could be a long-term legacy of radioactivity.”

Industry has made efforts to reuse or to transport shale gas wastewater to deep injection wells, but wastewater is still discharged to the environment in some states.

“It is clear that this practice of releasing wastewater without adequate treatment should be stopped in order to protect freshwater resources in areas of oil and gas development,” Vengosh says.

The Josephine Brine Treatment Facility is located in Indiana County, about an hour east of Pittsburgh. Blacklick Creek is a tributary of the Conemaugh River, which flows into the Allegheny River, a water source for numerous western Pennsylvania cities, including Pittsburgh.

The Nicholas School and the Park Foundation funded the study.

Source: Duke University

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