UC DAVIS (US) — Computer simulations show pressure-treating silicon could substantially improve the efficiency of solar cells.
Solar cells are based on the photoelectric effect: a photon, or particle of light, hits a silicon crystal and generates a negatively charged electron and a positively charged hole. Collecting those electron-hole pairs generates electric current.
Conventional solar cells generate one electron-hole pair per incoming photon, and have a theoretical maximum efficiency of 33 percent. One exciting new route to improved efficiency is to generate more than one electron-hole pair per photon, says Giulia Galli, professor of chemistry at the University of California, Davis and co-author of the paper.
“This approach is capable of increasing the maximum efficiency to 42 percent, beyond any solar cell available today, which would be a pretty big deal,” says Stefan Wippermann, lead author of the study published in Physical Review Letters.
“In fact, there is reason to believe that if parabolic mirrors are used to focus the sunlight on such a new-paradigm solar cell, its efficiency could reach as high as 70 percent,” Wippermann says.
Nanoparticles have a size of nanometers, typically just a few atoms across, Galli says. Because of their small size, many of their properties are different from bulk materials. In particular, the probability of generating more than one electron-hole pair is much enhanced, driven by an effect called “quantum confinement.”
Experiments to explore this paradigm are being pursued by researchers at the Los Alamos National Laboratory, the National Renewable Energy Laboratory in Golden, Colorado, as well.
“But with nanoparticles of conventional silicon, the paradigm works only in ultraviolet light,” Wippermann says. “This new approach will become useful only when it is demonstrated to work in visible sunlight.”
The researchers simulated the behavior of a structure of silicon called silicon BC8, which is formed under high pressure but is stable at normal pressures, much as diamond is a form of carbon formed under high pressure but stable at normal pressures.
The computer simulations were run through the National Energy Research Scientific Supercomputing Center at the Lawrence Berkeley Laboratory, which granted the project 10 million hours of supercomputer time.
The simulations demonstrated that nanoparticles of silicon BC8 indeed generate multiple electron-hole pairs per photon even when exposed to visible light.
“This is more than an academic exercise. A Harvard-MIT paper showed that when normal silicon solar cells are irradiated with laser light, the energy the laser emits may create a local pressure high enough to form BC8 nanocrystals. Thus, laser or chemical pressure treatment of existing solar cells may turn them into these higher-efficiency cells,” says co-author Gergely Zimanyi, professor of physics.
Researchers from the Budapest University of Technology and Economics contributed to the study, which received support from the National Science Foundation.
Source: UC Davis